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664979 Sigma-Aldrich

Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)

95%

Synonym: Dichlorobis[2-(diphenylphosphino-κP)ethanamine-κN]ruthenium

  • CAS Number 506417-41-0

  • Empirical Formula (Hill Notation) C28H32Cl2N2P2Ru

  • Molecular Weight 630.49

  •  MDL number MFCD07782004

  •  PubChem Substance ID 24884703

  •  NACRES NA.22

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Properties

Related Categories Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents,
Quality Level   100
assay   95%
reaction suitability   core: ruthenium
  reagent type: catalyst
mp   130-135 °C
SMILES string   Cl[Ru]Cl.NCCP(c1ccccc1)c2ccccc2.NCCP(c3ccccc3)c4ccccc4
InChI   1S/2C14H16NP.2ClH.Ru/c2*15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;;;/h2*1-10H,11-12,15H2;2*1H;/q;;;;+2/p-2
InChI key   BJNVYFXBTNBKRU-UHFFFAOYSA-L

Description

Application

Catalyst for:
• Synthesis of long chain linear fatty acid esters
• Preparation of ruthenium borohydride complexes for use in hydrogenation reactions
• Dehydrogenation of ammonia boranes
• Chemoselective reduction of carboxylic esters
• Synthesis of ruthenium beta-aminophosphine hydrido/chloro complexes with catalytic activities

Packaging

1 g in glass bottle

250 mg in glass bottle

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Articles

Aminophosphine Ligands

An increased interest in aminophosphine type ligands used for asymmetric synthesis has been witnessed. This growth in popularity of aminophosphine ligands in asymmetric synthesis is in part due to th...
William Sommer and Daniel Weibel

Keywords: Agrochemicals, Asymmetric synthesis, Catalysis, Hydrogenations, Industries, Ligands, Pharmaceutical

Ester Hydrogenation

The reduction of esters to alcohols is typically accomplished using metal hydrides. While effective, this widely used method comes at the cost of stoichiometric waste and often complicated workup pro...
Keywords: Catalysis, Hydrogenations, Reductions

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