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665029 Sigma-Aldrich

1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium chloride

Synonym: 1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride

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Description

Application

Reactant for:
• Preparation of chelated ruthenium alkoxybenzylidene imidazolidene carbene pivalate catalysts for Z-selective olefin metathesis
• Use in ring-opening metathesis polymerization and ring-closing metathesis reactions via Grubbs catalyst mediated reactions
• Preparation of adamantyl-substituted N-heterocyclic carbene ligands in second-generation Grubbs-type iridium metathesis catalysis

Packaging

100, 500 mg in glass bottle

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

NHC-Based Pd Catalysts and Ligands for C–C Bond Formation

Sigma-Aldrich, in collaboration with Umicore,1 is pleased to offer a series of robust Pd(II) and Pd(0) complexes employed as efficient catalysts in C–C bond forming reactions. The high performance Pd...
Aldrich ChemFiles 2006, 6.1, 8.
Keywords: Applications, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Coupling reactions, Ligands

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