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665134 Sigma-Aldrich

Oxotrichloro[bis(diphenylphosphino)methane]rhenium(V)

Synonym: Trichloro[methylenebis[diphenylphosphine]-P,P′]oxorhenium

  • CAS Number 60260-17-5

  • Empirical Formula (Hill Notation) C25H22Cl3OP2Re

  • Molecular Weight 692.96

  •  MDL number MFCD08276863

  •  PubChem Substance ID 24884715

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhenium Catalysts More...
InChI Key   SAVOOVLDSRTAGJ-UHFFFAOYSA-K

Description

Application

Catalyst for:
• Epoxidation of olefins using hydrogen peroxide activated bicarbonate as an oxidant
• Efficient reduction of aromatic sulfoxides
• Regioselective coupling of propargyl alcohols with sulfonamides and carbamates
• Cycloisomerization reactions

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Rhenium-Oxo Catalysts

Rhenium(V) forms a large number of stable octahedral complexes with multiple bonds to oxygen with traditional Re systems focusing on formal, stoichiometric oxygen atom transfer to organic reductants ...
Aldrich ChemFiles 2006, 6.1, 3.
Keywords: Addition reactions, Alkylations, Building blocks, Catalysis, Coupling reactions, Etherifications, Glycosylations, Ligands, Metathesis, Oxidations, Rearrangements, Solvents, Substitutions, Tools

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