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665150 Sigma-Aldrich

Ethyl N-Boc-piperidine-4-carboxylate

97%

Synonym: Ethyl 1-(tert-Butyloxycarbonyl)isonipecotate, Ethyl 1-(tert-butoxycarbonyl)-4-piperidinecarboxylate, Piperidine-1,4-dicarboxylic acid 1-tert-butyl ester 4-ethyl ester

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Properties

Related Categories Building Blocks, C13, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines More...
Quality Level   100
assay   97%
refractive index   n20/D 1.458
bp   120-135 °C/0.5 mmHg
density   1.046 g/mL at 25 °C
SMILES string   CCOC(=O)C1CCN(CC1)C(=O)OC(C)(C)C
InChI   1S/C13H23NO4/c1-5-17-11(15)10-6-8-14(9-7-10)12(16)18-13(2,3)4/h10H,5-9H2,1-4H3
InChI key   MYHJCTUTPIKNAT-UHFFFAOYSA-N

Description

Packaging

5, 25 g in glass bottle

Application

Substrate used in a palladium-catalyzed α-arylation of esters with heterocyclic bromides and chlorides leading to, for example, 4-pyridylpiperidinyl esters.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
230.0 °F - closed cup
Flash Point(C) 
> 110 °C - closed cup

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Peer-Reviewed Papers
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References

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