• USA Home
  • 665363 - (S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

EMAIL THIS PAGE TO A FRIEND
665363 Aldrich

(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

95% (HPLC)

Synonym: (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, (11bS)

Purchase

Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DSM MonoPhos Phosphoramidites, Privileged Ligands and Complexes More...
InChI Key   LKZPDRCMCSBQFN-CLJLJLNGSA-N
assay   95% (HPLC)
mp   102-103 °C

Description

Application

Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors. Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation.

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Packaging

100, 500 mg in glass insert

2 g in glass bottle

Legal Information

Sold under license from DSM for research purposes only.

MonoPhos is a registered trademark of DSM IP Assets B.V.

Features and Benefits

Advantages of the MonoPhos® ligands:
• Superior enantiocontrol in numerous transformations
• High activities at low catalyst loadings
• Hydrogenations under low-pressure conditions

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

DSM MonoPhos™ Family - Highly Efficient Privileged Ligands

Feringa and co-workers have invented a diverse array of chiral, monodentate phosphoramidites based on the privileged BINOL platform.1 The MonoPhos™ family has exhibited high levels of enantiocontrol ...
Aldrich ChemFiles 2006, 6.4, 15.
Keywords: Addition reactions, Alkylations, Asymmetric synthesis, Catalysis, Chemfiles, Desymmetrizations, Hydrogenations, Ligands

DSM MonoPhos™

In collaboration with DSM, we are pleased to offer a range of MonoPhos™ ligands for the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate phosphorami...
ChemFiles 2006, 6.8, 7.
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Asymmetric synthesis, Building blocks, Catalysis, Cyclizations, Desymmetrizations, Drug discovery, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations, Substitutions

Related Content

DSM MonoPhos Family- Highly Efficient Privileged Ligands

Aldrich, in our collaboration with DSM, is pleased to offer a range of MonoPhos™ ligands for the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate ph...
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Applications, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Cyclizations, Desymmetrizations, Drug discovery, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations, Substitutions

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?