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  • 665460 - (3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

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665460 Sigma-Aldrich

(3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

96%

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DSM MonoPhos Phosphoramidites, Privileged Ligands and Complexes More...
InChI Key   DRPNADVMTMEWQY-LOYHVIPDSA-N
assay   96%
mp   218-221 °C

Description

Application

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Phosphoramidite ligand employed in an asymmetric, iridium-catalyzed, allylic allylation of propenylboronates. Also used in a copper-catalyzed asymmetric conjugate addition of diethylzinc to α,β-unsaturated imines derived from amino acids.

Packaging

100 mg in clear glass bottle

500 mg in amber glass bottle

Legal Information

Sold under license from DSM for research purposes only.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

DSM MonoPhos™ Family - Aldrich ChemFiles 2008, 8.2, 51.

Feringa and co-workers have developed a diverse array of chiral, monodentate phosphoramidites based on the privileged BINOL platform.1 The MonoPhos™ family has exhibited high levels of enantiocontrol...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 51.
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Asymmetric synthesis, Catalysis, Chemfiles, Cyclizations, Desymmetrizations, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations

DSM MonoPhos™ Family - Highly Efficient Privileged Ligands

Feringa and co-workers have invented a diverse array of chiral, monodentate phosphoramidites based on the privileged BINOL platform.1 The MonoPhos™ family has exhibited high levels of enantiocontrol ...
Aldrich ChemFiles 2006, 6.4, 15.
Keywords: Addition reactions, Alkylations, Asymmetric synthesis, Catalysis, Chemfiles, Desymmetrizations, Hydrogenations, Ligands

DSM MonoPhos™

In collaboration with DSM, we are pleased to offer a range of MonoPhos™ ligands for the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate phosphorami...
ChemFiles 2006, 6.8, 7.
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Asymmetric synthesis, Building blocks, Catalysis, Cyclizations, Desymmetrizations, Drug discovery, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations, Substitutions

Related Content

DSM MonoPhos Family- Highly Efficient Privileged Ligands

In collaboration with DSM, we are pleased to offer a range of MonoPhos™ ligands to the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate phosphoramid...
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Asymmetric synthesis, Building blocks, Catalysis, Cyclizations, Desymmetrizations, Drug discovery, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations, Substitutions

Peer-Reviewed Papers
15

References

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