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  • 665533 - trans-2-(3-Chlorophenyl)vinylboronic acid pinacol ester

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665533 Sigma-Aldrich

trans-2-(3-Chlorophenyl)vinylboronic acid pinacol ester

97%

Synonym: 2-(E-2-(3-Chlorophenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

  • CAS Number 871125-84-7

  • Empirical Formula (Hill Notation) C14H18BClO2

  • Molecular Weight 264.56

  •  MDL number MFCD08276867

  •  PubChem Substance ID 24884746

  •  NACRES NA.22

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Properties

Related Categories Alkenyl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   NZBKTAJNGYXYSQ-CMDGGOBGSA-N
assay   97%
refractive index   n20/D 1.536
bp   138-140 °C/0.9-1.0 mmHg
density   1.049 g/mL at 25 °C

Description

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C
Protocols & Articles

Articles

Boronic Acid Esters - Chemfiles Volume 4 Article 2

The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura et al. demonst...
Chemfiles Volume 4 Article 2
Keywords: Coupling reactions, Suzuki-Miyaura coupling

Suzuki Coupling | ChemFiles 2006, 6.2, 10.

C–C bond formation via the Suzuki–Miyaura reaction is one of the most powerful and thoroughly explored facets of Pdcatalyzed cross-coupling. The boron-based nucleophiles utilized in this reaction off...
ChemFiles 2006, 6.2, 10.
Keywords: Addition reactions, C-C bond formation, Coupling reactions, Cross couplings, Epoxidations, Halogenations, Ligands, Microwave synthesis, Ozonolysis, Suzuki coupling, Vinylations

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