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665932 Sigma-Aldrich

2-[Bis(triphenylphosphine)palladium(II)bromide]benzyl alcohol

96%

Synonym: Bromo[2-(hydroxymethyl)phenyl]bis(triphenylphosphine) palladium

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
assay   96%
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
mp   190-193 °C (dec.)
SMILES string   OCc1ccccc1[Pd]Br.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
InChI   1S/2C18H15P.C7H7O.BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;8-6-7-4-2-1-3-5-7;;/h2*1-15H;1-4,8H,6H2;1H;/q;;;;+1/p-1
InChI key   JMCVBMDKKKGSJD-UHFFFAOYSA-M

Description

Application

Reactant for transformation into benzolactones on carbonylation

Catalyst for the low pressure carbonylation of aryl halides leading to phenylacetic acids in near quantitative yield.

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Catalysts
Protocols & Articles

Articles

Palladium Catalysts for Carbonylation

Metal-catalyzed carbonylation functions as one primary and efficient route for introducing carbonyl groups into an organic molecule. The versatility of carbonylation technology has been extended to t...
Chemfiles Volume 6 Article 1
Keywords: Carbonylations, Catalysis, Esterifications

Peer-Reviewed Papers
15

References

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