• USA Home
  • 666246 - 1-(2-Methoxyethoxy)-1-vinylcyclopropane

EMAIL THIS PAGE TO A FRIEND
666246 Aldrich

1-(2-Methoxyethoxy)-1-vinylcyclopropane

Synonym: 1-Ethenyl-1-(2-methoxyethoxy)cyclopropane

Purchase

Properties

Related Categories Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks More...
InChI Key   YIUPAIQJWAOJKD-UHFFFAOYSA-N
refractive index   n20/D 1.441
density   0.922 g/mL at 25 °C
storage temp.   2-8°C

Description

Application

A useful scaffold for the preparation of 7-membered and bicyclic ring systems.

Capable of participating in a variety of rhodium-catalyzed cycloaddition reactions.

Reactant for:
• Rhodium-catalyzed [5+2] cycloaddition with alkynes and allenes
• Cycloaddition/Nazarov cyclization sequence reactions
• Preparation of cyclohexenones by cocyclization with carbon monoxide catalyzed by octacarbonyldicobalt
• Preparation of cyclopentenes by nickel-catalyzed isomerization

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
114.8 °F
Flash Point(C) 
46 °C

Meet Synthia - Retrosynthesis Sofware
Protocols & Articles

Articles

Cycloaddition Reagents

Vinylcyclopropanes (VCPs) are excellent scaffolds for construction of seven-membered and bicyclic ring systems. Paul Wender, of Stanford University, has developed a simple but versatile VCP reagent (...
Aldrich ChemFiles 2006, 6.2, 8.
Keywords: Catalysis, Chemfiles, Cycloadditions

Peer-Reviewed Papers
15

References

Related Products

accessory

Product #

Description

Add to Cart

Z693847 Scienceware® Break-Safe ampule opener

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?