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667951 Sigma-Aldrich

(4-Methoxyphenyl)dimethylsilanol

96%

Synonym: (p-Methoxyphenyl)dimethylsilanol

  • CAS Number 22868-26-4

  • Linear Formula ((CH3O)C6H4)Si(CH3)2OH

  • Molecular Weight 182.29

  •  MDL number MFCD08276887

  •  PubChem Substance ID 24884950

  •  NACRES NA.22

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Properties

Related Categories Chemical Synthesis, Organometallic Reagents, Organosilicon, Silanols
InChI Key   DDLYKNBMTGBOQY-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.522
density   1.101 g/mL at 25 °C
storage temp.   2-8°C

Description

Packaging

1, 5 g in glass bottle

Application

A useful silicon nucleophile for Pd-catalyzed cross-coupling.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C
Protocols & Articles

Articles

Organosilanes for Cross-coupling

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg),...
ChemFiles 2006, 6.5, 7.
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Coupling reactions, Cross couplings, Grignard Reaction, Ligands, Metallations, Methods, Protocols, Silylations, Vinylations

Related Content

Organosilanols in Chemical Synthesis

Powerful Nucleophiles for Cross-Coupling Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to...
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Chemfiles, Coupling reactions, Cross couplings, Hiyama Coupling, Hydrosilylations, Ligands, Metallations, Methods, Protocols, Silylations

Peer-Reviewed Papers
15

References

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