• USA Home
  • 669156 - Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)

EMAIL THIS PAGE TO A FRIEND
669156 Sigma-Aldrich

Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)

Synonym: Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

  • CAS Number 677736-23-1

  • Empirical Formula (Hill Notation) C37H25ClO2Ru

  • Molecular Weight 638.12

  •  MDL number MFCD09265041

  •  PubChem Substance ID 24885021

  •  NACRES NA.22

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
mp   152-167 °C
reaction suitability   reagent type: catalyst
SMILES string   Cl[Ru].[C-]#[O+].[C-]#[O+].c1ccc(cc1)[C]2[C]([C]([C]([C]2c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6
InChI   1S/C35H25.2CO.ClH.Ru/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;2*1-2;;/h1-25H;;;1H;/q;;;;+1/p-1
InChI key   NGSBLRJKXUHTOC-UHFFFAOYSA-M

Description

Application

Reactant for:
• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
• Ligand exchange
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:
• (S)-Selective dynamic kinetic resolution of secondary alcohols
• Stereoselective synthesis of neonicorinoide pesticide derivatives
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines

Packaging

100 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number
Protocols & Articles
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?