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  • 669180 - (R)-(−)-3,3′-Bis(3,5-dimethylphenyl)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2-naphthol

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669180 Sigma-Aldrich

(R)-(−)-3,3′-Bis(3,5-dimethylphenyl)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2-naphthol

97%

Synonym: (R)-3,3′-Bis(3,5-dimethylphenyl)-5,6,7,8,5′,6′,7′,8′-octahydro-[1,1′]binaphthalenyl-2, 2′-diol

  • Empirical Formula (Hill Notation) C36H38O2

  • Molecular Weight 502.69

  •  MDL number MFCD08457658

  •  PubChem Substance ID 24885025

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Organocatalysts,
assay   97%
mp   218-222 °C
InChI   1S/C36H38O2/c1-21-13-22(2)16-27(15-21)31-19-25-9-5-7-11-29(25)33(35(31)37)34-30-12-8-6-10-26(30)20-32(36(34)38)28-17-23(3)14-24(4)18-28/h13-20,37-38H,5-12H2,1-4H3
InChI key   RSHMDLJRFPHHRE-UHFFFAOYSA-N

Description

Packaging

100 mg in clear glass bottle

Safety & Documentation

Safety Information

Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

BINOL and Derivatives

BINOL and its derivatives are one of the mostly widely used classes of ligands in asymmetric synthesis; being utilized in a broad array of reactions including: Diels–Alder, carbonyl addition and redu...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 56.
Keywords: Addition reactions, Alkylations, Amidations, Asymmetric synthesis, Building blocks, Catalysis, Cycloadditions, Diels-Alder reaction, Ligands, Methods, Organic synthesis, Reductions

Chiral Diols - Aldrich ChemFiles 2007, 7.9, 13.

Apart from numerous examples using TADDOLs in metal-catalyzed asymmetric reactions, Rawal recently reported that TADDOLs could be used as Brønsted acid organocatalysts in highly stereoselective heter...
Aldrich ChemFiles 2007, 7.9, 13.
Keywords: Addition reactions, Aminations, Asymmetric synthesis, Catalysis, Substitutions

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