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673250 Sigma-Aldrich

Sodium 2-furyldimethylsilanolate

Synonym: Dimethyl-2-furylsilanol sodium salt, Sodium 2-furanyldimethylsilanolate

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Properties

Related Categories Chemical Synthesis, Organometallic Reagents, Organosilicon, Silanols
mp   65-80 °C
SMILES string   [Na+].C[Si](C)([O-])c1ccco1
InChI   1S/C6H9O2Si.Na/c1-9(2,7)6-4-3-5-8-6;/h3-5H,1-2H3;/q-1;+1
InChI key   LZJRCLPTAZMQQW-UHFFFAOYSA-N

Description

Application

A useful silicon nucleophile for Pd-catalyzed cross-coupling.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Organosilanes for Cross-coupling

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg),...
ChemFiles 2006, 6.5, 7.
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Coupling reactions, Cross couplings, Grignard Reaction, Ligands, Metallations, Methods, Protocols, Silylations, Vinylations

Related Content

Organosilanols in Chemical Synthesis

Powerful Nucleophiles for Cross-Coupling Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to...
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Chemfiles, Coupling reactions, Cross couplings, Hiyama Coupling, Hydrosilylations, Ligands, Metallations, Methods, Protocols, Silylations

Peer-Reviewed Papers
15

References

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