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677876 Sigma-Aldrich

Trichloro(pyridine)gold(III)

97%

Synonym: (Pyridine)gold trichloride

  • CAS Number 14911-01-4

  • Empirical Formula (Hill Notation) C5H5AuCl3N

  • Molecular Weight 382.43

  •  MDL number MFCD00064726

  •  eCl@ss 39151701

  •  PubChem Substance ID 24885401

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
assay   97%
mp   232-240 °C
reaction suitability   reagent type: catalyst
SMILES string   Cl[Au](Cl)Cl.c1ccncc1
InChI   1S/C5H5N.Au.3ClH/c1-2-4-6-5-3-1;;;;/h1-5H;;3*1H/q;+3;;;/p-3
InChI key   TYJJOEBQRJABJG-UHFFFAOYSA-K

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Gold Catalysts — 21st Century ′Gold Rush′

• An N-stabilized gold(III) catalyst employed in a synthesis of tetrahydroisoquinolines.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions

Peer-Reviewed Papers
15

References

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