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677922 Sigma-Aldrich

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct

Synonym: [Bis(trifluoromethanesulfonyl)imidate](PPh3)gold(I) (2:1) toluene adduct

  • Linear Formula (C20H15AuF6NO4PS2) 2 · C7H8

  • Molecular Weight 1570.93

  •  MDL number MFCD09038445

  •  PubChem Substance ID 24885406

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
Quality Level   100
reaction suitability   reagent type: catalyst
SMILES string   [Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI   1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1
InChI key   SIVCTOVPPFSWEF-UHFFFAOYSA-N

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

DuPhos and BPE Phospholane Ligands

Asymmetric hydrogenation reactions represent the ideal process for the commercial manufacture of single-enantiomer compounds, because of the ease by which these robust procedures can be scaled up and...
Aldrich ChemFiles 2006, 6.8, 3.
Keywords: Addition reactions, Alkylations, Allylborations, Amidations, Aminations, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Crotylborations, Cycloadditions, Electronics, Hydrogenations, Ligands, Purification, Reductions, Reductive aminations, transformation

Tom Sheppard Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Tom Sheppard Group - Professor Product Portal
Keywords: Amidations, Arylations, Catalysis, Chemical reactions, Chromatography, Dehydration reaction, Organocatalysis, Substitutions

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions

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