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  • 678023 - 4,7-Dimethoxy-1,10-phenanthroline

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678023 Sigma-Aldrich

4,7-Dimethoxy-1,10-phenanthroline

97%

  • CAS Number 92149-07-0

  • Empirical Formula (Hill Notation) C14H12N2O2

  • Molecular Weight 240.26

  •  MDL number MFCD00233883

  •  PubChem Substance ID 24885413

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C9 to C20+, Catalysis and Inorganic Chemistry, Chemical Synthesis, Organic Building Blocks,
Quality Level   100
assay   97%
mp   197-212 °C
reaction suitability   reagent type: ligand
SMILES string   COc1ccnc2c1ccc3c(OC)ccnc23
InChI   1S/C14H12N2O2/c1-17-11-5-7-15-13-9(11)3-4-10-12(18-2)6-8-16-14(10)13/h3-8H,1-2H3
InChI key   ZPGVCQYKXIQWTP-UHFFFAOYSA-N

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Ligand for Cu-catalzyed N-arylation of imidazoles

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

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Protocols & Articles

Articles

Buchwald Ligands for C–N Coupling

Although many methodologies have been developed for C–N coupling reactions, until recently there were no general methods available for the N-arylation of imidazoles. Traditional methods for arylation...
Aldrich ChemFiles 2007, 7.1, 8.
Keywords: Arylations, Catalysis, Coupling reactions, Ligands, Methods, Nucleophilic aromatic substitution, Substitutions, Type

Buchwald Phosphine Ligands - Technical Article

Over the past several years, the Buchwald group has developed a series of bulky electron-rich phosphines that have garnered much attention for their ability to effect various C–C, C–N, and C–O bond f...
Keywords: Aldrichimica Acta, Arylations, C-X bond formation, Catalysis, Chemfiles, Coupling reactions, Ligands, Methods, Type

Related Content

Buchwald Phosphine Ligands - For C-C, C-N, and C-O Bond Formation

For C-C, C-N, and C-O Bond Formation: Over the past several years, the Buchwald group has developed a series of bulky electron-rich phosphines that have garnered much attention for their ability to e...
Keywords: Arylations, C-X bond formation, Catalysis, Coupling reactions, Ligands

Peer-Reviewed Papers
15

References

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