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678414 Sigma-Aldrich

O-Allyl 2,2,2-trichloroacetimidate

96%

Synonym: 2,2,2-Trichloroacetimidic acid allyl ester

  • CAS Number 51479-73-3

  • Empirical Formula (Hill Notation) C5H6Cl3NO

  • Molecular Weight 202.47

  •  Beilstein Registry Number 1907084

  •  MDL number MFCD00190710

  •  PubChem Substance ID 24885427

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Properties

Related Categories Amidates/Imidates, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks,
InChI Key   UJYZRNWTLPBNOR-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.489
bp   54-70 °C/7.5-11.25 mmHg
density   1.333 g/mL at 25 °C
storage temp.   2-8°C

Description

Packaging

5 g in glass bottle

Application

Reagent used for the protection of an alcohol as its allyl ether in the presence of base sensitive functionality.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
WGK Germany 
3
Flash Point(F) 
163.4 °F
Flash Point(C) 
73 °C

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Protocols & Articles

Articles

Trichloroacetimidate Reagents

As described previously, trichloroacetimidates are also commonly employed as alcohol alkylation reagents, particularly when existing functionality is not acid sensitive.1 Recent applications of allyl...
Aldrich ChemFiles 2007, 7.3, 4.
Keywords: Alkylations, Organic synthesis

Peer-Reviewed Papers
15

References

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