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678635 Sigma-Aldrich

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide

kanata purity

Synonym: (2R,5R)-1-{2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide, R,R-Me-BozPhos

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes More...
InChI Key   ORZVYNTUPREFTI-KLHDSHLOSA-N
optical activity   [α]22/D -171°, c = 1 in chloroform
mp   116-122 °C

Description

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Packaging

100 mg in clear glass bottle

500 mg in amber glass bottle

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

DuPhos and BPE Phospholane Ligands and Complexes

In the early 1990s, Burk and coworkers developed new electron-rich C2 symmetric bis(phospholane) ligands. The modular nature of these ligands allowed for variation of both phosphane substituent and b...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 34.
Keywords: Aminations, Applications, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Crotylborations, Hydrogenations, Ligands, Reductions, Reductive aminations

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