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682691 Sigma-Aldrich

Bis(tri-tert-butylphosphine)platinum(0)

Synonym: Bis[tris(1,1-dimethylethyl)phosphine]platinum

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Platinum Catalysts More...
Quality Level   100
reaction suitability   core: platinum
  reagent type: catalyst
mp   260-269 °C
storage temp.   2-8°C
SMILES string   [Pt].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI   1S/2C12H27P.Pt/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
InChI key   RJQWVEJVXWLMRE-UHFFFAOYSA-N

Description

Application

Reactant for synthesis of:
• Trimetallic ReBiPt complexes
• Rhodium-germanium carbonyl complexes

Catalyst for the synthesis of:
• Amidobipyridyl inhibitors of protein kinase D
• 5-Fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling

Catalyst for phenyl and methyl group transfer from tin to iridium

Activator of metal hydride complexes

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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