• USA Home
  • 683175 - Bis(norbornadiene)rhodium(I) tetrafluoroborate

EMAIL THIS PAGE TO A FRIEND
683175 Sigma-Aldrich

Bis(norbornadiene)rhodium(I) tetrafluoroborate

Synonym: Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate, Bis(norbornadiene)(tetrafluoroborato)rhodium, Rh(nbd)2BF4, Rh(nbd)2BF4

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
Quality Level   100
reaction suitability   reagent type: catalyst
mp   136.9-139.9 °C
SMILES string   [Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4
InChI   1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;
InChI key   HAYDJWBQWOEERB-JAGGYEKFSA-N

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Bis(norbornadiene)rhodium(I) tetrafluoroborate can be used as a catalyst for the synthesis of:
• Lactones via the 1,4-addition of arylboronic acids to butenolide.
• Chiral β-aryl-substituted ketones and esters.
• β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.

Packaging

2 g in poly bottle

500 mg in poly bottle

Legal Information

A product of Umicore

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1759 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number

Certificate of Origin (COO)

Please Enter a Lot Number

Catalysts
Protocols & Articles

Related Content

Umicore Precatalysts

Introduction Sigma-Aldrich and Umicore are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross-coupling catalysis. Our partnership with Umicore allows us to offer a po...
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Cross couplings, Hydrogenations, Infrared spectroscopy, Ligands, Methods, Reductions, transformation

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?