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683183 Sigma-Aldrich

(Acetylacetonato)dicarbonylrhodium(I)

98%

Synonym: Dicarbonyl-acetylacetonato-rhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rh(CO)2acac, Rhodium(I) dicarbonyl acetylacetonate

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
Quality Level   100
assay   98%
form   solid
reaction suitability   reagent type: catalyst
mp   154-156 °C (lit.)
SMILES string   [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
InChI   1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChI key   BZCAWKOPWNIDOC-FGSKAQBVSA-M

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds

Packaging

2 g in glass bottle

500 mg in glass bottle

Legal Information

Product of Umicore

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Supplemental Hazard Statements 
EUH044
Personal Protective Equipment 
RIDADR 
UN 3467 6.1 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Catalysts
Protocols & Articles

Related Content

Umicore Precatalysts

Introduction Sigma-Aldrich and Umicore are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross-coupling catalysis. Our partnership with Umicore allows us to offer a po...
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Cross couplings, Hydrogenations, Infrared spectroscopy, Ligands, Methods, Reductions, transformation

Peer-Reviewed Papers
15

References

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