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683345 Sigma-Aldrich

Tris(dibenzylideneacetone)dipalladium(0)

Synonym: Pd2(dba)3, Pd2dba3

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Properties

Related Categories Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Homogeneous Pd Catalysts,
InChI Key   CYPYTURSJDMMMP-WVCUSYJESA-N
mp   152-155 °C (lit.)
storage temp.   2-8°C

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for C-C and C-N bond formation especially Suzuki, Heck coupling reaction

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
• Preparation of palladium triphenylphosphine carbonyl cluster complexes
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes

Catalyst for:
• Suzuki cross-coupling reactions
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation

Packaging

5 g in glass bottle

500 mg in glass bottle

Legal Information

Product of Umicore

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
2
Protocols & Articles

Related Content

Umicore Precatalysts

Introduction Sigma-Aldrich and Umicore are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross-coupling catalysis. Our partnership with Umicore allows us to offer a po...
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Cross couplings, Hydrogenations, Infrared spectroscopy, Ligands, Methods, Reductions, transformation

Peer-Reviewed Papers
15

References

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