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683353 Sigma-Aldrich

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

Green Alternative

Synonym: (1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium, Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium, Ru(Me-allyl)2(COD), Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex

  • CAS Number 12289-94-0

  • Linear Formula Ru(methylallyl)2(COD)

  • Molecular Weight 319.45

  •  MDL number MFCD00216965

  •  PubChem Substance ID 329760814

  •  NACRES NA.22

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Properties

Related Categories 12 Principles Aligned Products, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Greener Catalysts,
Quality Level   100
reaction suitability   reagent type: catalyst
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   81.7-82.4 °C (lit.)
storage temp.   −20°C
SMILES string   C1CC=CCCC=C1.CC(=C)C[Ru]CC(C)=C
InChI   1S/C8H12.2C4H7.Ru/c1-2-4-6-8-7-5-3-1;2*1-4(2)3;/h1-2,7-8H,3-6H2;2*1-2H2,3H3;/b2-1-,8-7-;;;
InChI key   GRYFGFSAXGLJLN-PHFPKPIQSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for greener amine synthesis by hydrogenation of nitriles.

A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles

Packaging

2 g in glass bottle

500 mg in glass bottle

Legal Information

A product of Umicore

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3395 4.3 / PGIII
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Catalysts
Protocols & Articles

Related Content

Umicore Precatalysts

Introduction Sigma-Aldrich and Umicore are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross-coupling catalysis. Our partnership with Umicore allows us to offer a po...
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Cross couplings, Hydrogenations, Infrared spectroscopy, Ligands, Methods, Reductions, transformation

Peer-Reviewed Papers
15

References

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