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683833 Sigma-Aldrich

2-Ethoxycarbonylphenylboronic acid

≥95%

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
Quality Level   100
assay   ≥95%
form   powder or crystals
mp   128-136 °C
SMILES string   CCOC(=O)c1ccccc1B(O)O
InChI   1S/C9H11BO4/c1-2-14-9(11)7-5-3-4-6-8(7)10(12)13/h3-6,12-13H,2H2,1H3
InChI key   QZKVVOXAEBCLPZ-UHFFFAOYSA-N

Description

Application

Reactant for:
• Synthesis of embelin derivatives via Suzuki-Miyaura reaction, cross metathesis and Wittig olefination
• Asymmetric cyclopropanation of alkenes with di-Me diazomalonate catalyzed by chiral diene-rhodium complexes
• Preparation of phenylalanines as selective AMPA- and kainate receptor ligands
• Preparation of aryl pyrazinones via microwave-assisted palladium-catalyzed arylation of resin supported pyrazinones under simultaneous cooling condition
• Regioselective preparation of (aryl)hydroxyquinolines via Suzuki-Miyaura cross-coupling with chloro(tosyloxy)quinoline under anhydrous conditions followed by nucleophilic deprotection of the tosyl group

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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905534 (2-(Phenoxycarbonyl)phenyl)boronic acid, ≥95%

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