• USA Home
  • 684821 - 1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate

EMAIL THIS PAGE TO A FRIEND
684821 Sigma-Aldrich

1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate

Green Alternative

Synonym: White catalyst

  • CAS Number 858971-43-4

  • Empirical Formula (Hill Notation) C18H20O6PdS2

  • Molecular Weight 502.90

  •  MDL number MFCD09842752

  •  PubChem Substance ID 329760926

  •  NACRES NA.22

Purchase

Properties

Related Categories 12 Principles Aligned Products, C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis,
Quality Level   100
reaction suitability   core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
storage temp.   −20°C
SMILES string   CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2
InChI   1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2
InChI key   SNNYSJNYZJXIFE-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

White Catalyst: A Catalyst for Allylic C–H Oxidation and Amination

Macrolactonization via Hydrocarbon Oxidation

Catalyst for allylic C-H oxidation, useful for preparation of branched allylic esters, macrocycles, and amino alcohol derivatives.

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Related Content

White catalyst

Allylic C–H Oxidation In 2004, the White group reported sulfoxide-promoted, catalytic Pd(II) / benzoquinonone / HOAc α-olefin allylic oxidation systems, wherein the ratio of linear-to-branched allyli...
Keywords: Aminations, Antitumor agents, Arylations, Catalysis, Heck Reaction, Isomerizations, Ligands, Oxidations

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?