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685054 Sigma-Aldrich

Cyclopentadienyl(η6-napthalene)ruthenium(II) hexafluorophosphate

  • CAS Number 102538-40-9

  • Linear Formula [(C5H5)Ru(C10H8)]PF6

  • Molecular Weight 439.30

  •  PubChem Substance ID 329760939

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
Quality Level   100
reaction suitability   core: ruthenium
  reagent type: catalyst
storage temp.   2-8°C
SMILES string   [Ru+].[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F.[CH]2[CH][CH][C]3C=CC=C[C]3[CH]2
InChI   1S/C10H8.C5H5.F6P.Ru/c1-2-6-10-8-4-3-7-9(10)5-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h1-8H;1-5H;;/q;;-1;+1
InChI key   GURCWALMXLWMQE-UHFFFAOYSA-N

Description

Packaging

1 g in poly bottle

250 mg in poly bottle

Application

Highly-active catalyst for anti-Markovnikov hydration of terminal alkynes. An alternative to CpRu(CH3CN)3+ PF6-.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Seth Herzon Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Seth Herzon Group - Professor Product Portal
Keywords: Addition reactions, Catalysis, Hydration reaction, Ligands, Separation, Solvents, transformation

Peer-Reviewed Papers
15

References

Related Products

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Description

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902144 [(Cp)Ru(η6-naphthalene)]OTf, ≥95%

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