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685062 Sigma-Aldrich

(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

Synonym: Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I), [Ir(OMe)(1,5-cod)]2

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Properties

Related Categories C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis,
InChI Key   BGWIAAATAAWGOI-MIXQCLKLSA-N
mp   154-179 °C (D)
storage temp.   −20°C

Description

Application

Catalyst for:
• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase
• Borylation/Suzuki-Miyaura coupling
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls
• Tetraborylation reactions
• Highly regio- and enantioselective asymmetric hydroboration
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation

A powerful C-H activation catalyst to prepare phenols from arenes

Packaging

1, 25 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

Ir(I)-Catalyzed C–H Borylation

Arylboronic acids and esters are invaluable tools for the chemical community. These powerful reagents are used for a variety of transformations, most notably the Suzuki-Miyaura cross-coupling reactio...
Josephine Nakhla
Chemfiles Volume 11 Article 1
Keywords: Catalysis, Coupling reactions, Cross couplings, Infrared spectroscopy

Peer-Reviewed Papers
15

References

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