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  • 685569 - (11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

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685569 Sigma-Aldrich

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

Synonym: MonoPhos Ligand

  • CAS Number 389130-06-7

  • Empirical Formula (Hill Notation) C22H26NO2P

  • Molecular Weight 367.42

  •  MDL number MFCD04117692

  •  PubChem Substance ID 329760980

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DSM MonoPhos Phosphoramidites, Privileged Ligands and Complexes More...
InChI Key   OIZQADYWBXZQKE-UHFFFAOYSA-N
optical activity   [α]22/D 282.0°, c = 1 in chloroform
mp   86-94 °C

Description

Application

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Packaging

100 mg in clear glass bottle

500 mg in amber glass bottle

Legal Information

Sold under license from DSM for research purposes only.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

DSM MonoPhos™ Family - Aldrich ChemFiles 2008, 8.2, 51.

Feringa and co-workers have developed a diverse array of chiral, monodentate phosphoramidites based on the privileged BINOL platform.1 The MonoPhos™ family has exhibited high levels of enantiocontrol...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 51.
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Asymmetric synthesis, Catalysis, Chemfiles, Cyclizations, Desymmetrizations, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations

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