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686441 Sigma-Aldrich

Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)

Synonym: Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

  • CAS Number 677736-23-1

  • Empirical Formula (Hill Notation) C37H25ClO2Ru

  • Molecular Weight 638.12

  •  MDL number MFCD09265041

  •  PubChem Substance ID 329761049

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
mp   152-167 °C
reaction suitability   reagent type: catalyst
SMILES string   Cl[Ru].[C-]#[O+].[C-]#[O+].c1ccc(cc1)[C]2[C]([C]([C]([C]2c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6
InChI   1S/C35H25.2CO.ClH.Ru/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;2*1-2;;/h1-25H;;;1H;/q;;;;+1/p-1
InChI key   NGSBLRJKXUHTOC-UHFFFAOYSA-M

Description

Application

Reactant for:
• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
• Ligand exchange
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:
• (S)-Selective dynamic kinetic resolution of secondary alcohols
• Stereoselective synthesis of neonicorinoide pesticide derivatives
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines

Packaging

1 g in glass bottle

250 mg in glass bottle

Citation

Metal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution

Legal Information

Product of Kanata Chemical Technologies, Inc.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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