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687561 Sigma-Aldrich

(Rp)-2-(tert-Butylthio)-1-(diphenylphosphino)ferrocene

98%

Synonym: (1S)-1-(tert-Butylthio)-2-(diphenylphosphino)ferrocene, (R)-FeSulPhos

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
InChI Key   IHULVPNADBGKMY-UHFFFAOYSA-N
assay   98%
mp   146-149 °C

Description

Application

Enantioselective allylic substitution, enantioselective 1,3-dipolar cycloaddition.

Packaging

100 mg in clear glass bottle

500 mg in amber glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Asymmetric 1,3-dipolar Cycloaddition Using Fesulphos

The asymmetric 1,3-dipolar cycloaddition reaction is of the utmost importance for the enantioselective synthesis of five-membered heterocycles. Cabrera et al. introduced a new family of ligands consi...
William Sommer
Aldrich ChemFiles 2008, 8.6, 14.
Keywords: 1,3-Dipolar cycloaddition, Asymmetric synthesis, Catalysis, Chemfiles, Cycloadditions, Ligands

Asymmetric Oxidation of Di-tert-butyl Disulfide

The seminal work of Ellman and coworkers provided the first example of the catalytic asymmetric oxidation of tert-butyl disulfide. The desymmetrization involves reaction of tert-butyl disulfide with ...
William Sommer
Aldrich ChemFiles 2008, 8.6, 14.
Keywords: Asymmetric synthesis, Catalysis, Chemfiles, Desymmetrizations, Ligands, Oxidations, Solvents

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