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688959 Sigma-Aldrich

(R,R)-Bicyclo[2.2.1]heptane-2,5-dione

98%

  • CAS Number 145092-77-9

  • Empirical Formula (Hill Notation) C7H8O2

  • Molecular Weight 124.14

  •  Beilstein/REAXYS Number 9477671

  •  PubChem Substance ID 329761205

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks More...
Quality Level   100
assay   ≥97.5% (GC)
  98%
optical activity   [α]/D 4.5±1.0°, c = 1 in chloroform
SMILES string   O=C1C[C@H]2C[C@@H]1CC2=O
InChI   1S/C7H8O2/c8-6-2-4-1-5(6)3-7(4)9/h4-5H,1-3H2/t4-,5-/m1/s1
InChI key   RVFBNLMXCXFOET-RFZPGFLSSA-N

Description

Packaging

500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Chiral Diene Ligands for Asymmetric Transformations

In the last few years, a number of chiral diene ligands have emerged for a variety of asymmetric transformations.1 This powerful new method has proven to be an efficient way for the construction of e...

ChemFiles 2010, 10.2, 4.


Keywords: Addition reactions, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Cross couplings, Hydrosilylations, Ligands, Oxidations, Swern Oxidation

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