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689661 Sigma-Aldrich

(1S,2S)-(+)-Norpseudoephedrine

≥98.0% (NT)

Synonym: (+)-Cathine, (+)-Pseudonorephedrine, (1S,2S)-2-Amino-1-phenyl-1-propanol, D-(+)-Norpseudoephedrine

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Properties

Related Categories Amino Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Chiral Building Blocks,
assay   ≥98.0% (NT)
optical activity   [α]/D +34.0±2.0°, c = 3.5 in ethanol
drug control   USDEA Schedule IV; regulated under CDSA - not available from Sigma-Aldrich Canada; psicótropo (Spain); Decreto Lei 15/93: Tabela IIB (Portugal)
storage temp.   2-8°C
SMILES string   C[C@H](N)[C@@H](O)c1ccccc1
InChI   1S/C9H13NO/c1-7(10)9(11)8-5-3-2-4-6-8/h2-7,9,11H,10H2,1H3/t7-,9+/m0/s1
InChI key   DLNKOYKMWOXYQA-IONNQARKSA-N

Description

Application

(1S,2S)-(+)-Norpseudoephedrine can be used:
• As a starting material for the synthesis of benzamide based ligands applicable in the Tsuji−Trost allylic alkylation reactions.
• To prepare its catalyst derivatives, which are applicable in the alkylation of benzaldehydes using diethylzinc.

Packaging

1, 5 g in glass bottle

Other Notes

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 689661.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

Safety & Documentation

Safety Information

Symbol 
GHS06  GHS06
Signal word 
Danger
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
RTECS 
RC9100000

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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