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691100 Sigma-Aldrich

(9-Benzyl-9-fluorenyl)dicyclohexylphosphonium tetrafluoroborate

95%

Synonym: (9-Benzyl-9-fluorenyl)dicyclohexylphosphine tetrafluoroborate, Dicyclohexyl[9-(phenylmethyl)-9H-fluoren-9-yl]phosphine tetrafluoroborate, cataCXium® FBn

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Properties

Related Categories Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Phosphine Compounds,
assay   95%
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
functional group   phosphine
storage temp.   room temp
SMILES string   F[B-](F)(F)F.C1CCC(CC1)[PH+](C2CCCCC2)C4(Cc3ccccc3)c5ccccc5-c6ccccc46
InChI   1S/C32H37P.BF4/c1-4-14-25(15-5-1)24-32(30-22-12-10-20-28(30)29-21-11-13-23-31(29)32)33(26-16-6-2-7-17-26)27-18-8-3-9-19-27;2-1(3,4)5/h1,4-5,10-15,20-23,26-27H,2-3,6-9,16-19,24H2;/q;-1/p+1
InChI key   TXCRCYKOFGNXQO-UHFFFAOYSA-O

Description

General description

sold in collaboration with Solvias AG

Application

Catalyst for Sonogashira, Suzuki, and Buchwald-Hartwig coupling reactions

Packaging

1, 5 g in glass bottle

Legal Information

cataCXium is a registered trademark of Evonik Degussa GmbH

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

cataCXium®

Cross-coupling reactions are an important class of catalytic transformations with applications in polymer science as well as in the fine chemicals and pharmaceutical industries. The use of aryl chlor...
William Sommer
ChemFiles Volume 7 Article 10
Keywords: Aminations, Applications, Buchwald-Hartwig amination, Catalysis, Coupling reactions, Cross couplings, Industries, Ligands, Pharmaceutical, Polymer science, Suzuki coupling, transformation

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