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692441 Sigma-Aldrich

(R)-[(RuCl(T-BINAP))2(μ-Cl)3[NH2Me2]

Synonym: Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]diruthenate(II)

  • CAS Number 749935-02-2

  • Linear Formula (CH3)2NH2+[C96H80Cl5P4Ru2]−

  • Molecular Weight 1783.05

  •  MDL number MFCD09753034

  •  PubChem Substance ID 329761498

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
Quality Level   100
storage temp.   2-8°C
SMILES string   Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3ccc(cc3)P(c4ccc(C)cc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccc(C)cc9)c%10ccc(C)cc%10.Cc%11ccc(cc%11)P(c%12ccc(C)cc%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17ccc(C)cc%17)c%18ccc(C)cc%18
InChI   1S/2C48H40P2.C2H7N.2ClH.3Cl.2Ru/c2*1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-3-2;;;;;;;/h2*5-32H,1-4H3;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1
InChI key   QGBBTZBFEYSGDQ-UHFFFAOYSA-M

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Packaging

100, 500 mg in amber glass bottle

Legal Information

Sold in collaboration with Takasago for research purposes only.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Takasago Ligands and Complexes for Asymmetric Reactions

The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of the most releva...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, transformation

Related Content

Takasago Ligands - Advantages and Applications

Introduction The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of th...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Epoxidations, Hydrogenations, Hydrosilylations, Ligands, Sharpless Epoxidation, transformation

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