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693456 Sigma-Aldrich

Shi Epoxidation Oxazolidinone Methyl Catalyst

95%

Synonym: (3aR,5′S,7aR)-Dihydro-2,2-dimethyl-3′-(4-methylphenyl)-spiro[6H-1,3-dioxolo[4,5-c]pyran-6,5′-oxazolidine]-2′,7(4H)-dione

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Epoxidation
InChI Key   WFKGDVVGAWYPFR-XNJGSVPQSA-N
assay   95%
optical activity   [α]22/D -28.0°, c = 1 in chloroform
mp   149-154 °C
storage temp.   2-8°C

Description

Packaging

100, 500 mg in amber glass bottle

Application

Asymmetric epoxidation organocatalyst

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Asymmetric Epoxidation Using Shi Catalyst | Technical Article

Catalytic asymmetric epoxidation of alkenes has been the focus of many research efforts over the past two decades, the best known methods probably being those developed by Sharpless1 and Jacobsen- Ka...
William Sommer
Aldrich ChemFiles 2008, 8.6, 13.
Keywords: Asymmetric synthesis, Catalysis, Chemfiles, Epoxidations, Ligands, Methods, Oxidations, Reductions, Shi Epoxidation

Shi Catalyst Asymmetric Epoxidation

Catalytic asymmetric epoxidation of alkenes has been the focus of many research efforts over the past two decades, the best known methods probably being those developed by Sharpless1 and Jacobsen-Kat...
Daniel Weibel
Aldrich ChemFiles 2010, 10.3, 5.
Keywords: Asymmetric synthesis, Catalysis, Epoxidations, Ligands, Methods, Oxidations, Reductions, Shi Epoxidation

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