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695173 Sigma-Aldrich

Dichloro(2-pyridinecarboxylato)gold

  • CAS Number 88215-41-2

  • Empirical Formula (Hill Notation) C6H4NAuCl2O2

  • Molecular Weight 389.97

  •  PubChem Substance ID 329761723

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
Quality Level   100
reaction suitability   core: gold
  reagent type: catalyst
mp   175-176 °C
SMILES string   Cl[Au]1(Cl)OC(=O)C2=[N]1C=CC=C2
InChI   1S/C6H5NO2.Au.2ClH/c8-6(9)5-3-1-2-4-7-5;;;/h1-4H,(H,8,9);;2*1H/q;+3;;/p-3
InChI key   PKAWSKSRAJXTIH-UHFFFAOYSA-K

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Intermolecular [4+3]-Annulation

In 2008, Toste and coworkers developed a new method to synthesize azepines using a Au(III) catalyst.1 Following the work done by the group with sulfoxides showing that the allylgold intermediate can ...
William Sommer
Aldrich ChemFiles 2009, 9.5, 4.
Keywords: Chemfiles, Cycloadditions

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions

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