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  • 695459 - 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

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695459 Sigma-Aldrich

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

97%

Synonym: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane, meCgPPh

  • CAS Number 97739-46-3

  • Empirical Formula (Hill Notation) C16H21O3P

  • Molecular Weight 292.31

  •  PubChem Substance ID 329761744

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Properties

Related Categories Buchwald Ligands and Complexes, Buchwald and Related Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
InChI Key   AVVSJWUWBATQBX-UHFFFAOYSA-N
assay   97%
mp   106-111 °C

Description

Packaging

2 g in glass bottle

500 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Hydroformylation

Despite a long-standing belief that formyl groups cannot be generated at quaternary carbon centers via hydroformylation, Clarke and Roff have developed a method utilizing 1,3,5,7-tetramethyl-6-phenyl...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 9.
Keywords: Chemfiles, Hydroformylations, Hydrogenations, Ligands

Trialkylphosphine for Morita-Baylis Hillman Reactions

The use of amines and phosphines in nucleophilic catalysis is well precedented; however, arguably one of the severe limitations with respect to exploiting the more nucleophilic, yet less basic, phosp...
Keywords: Catalysis, Organocatalysis

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