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696064 Sigma-Aldrich

(S)-C3-TunePhos

Synonym: (S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin

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Description

Application

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Reactant for:
• Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes
• Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates

Precatalyst for:
• Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate

Catalyst for:
• Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts

Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters, cyclic β-(acylamino)acrylates and a-phthalimide ketones.

Packaging

100, 500 mg in amber glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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