• USA Home
  • 696307 - Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)

EMAIL THIS PAGE TO A FRIEND
696307 Sigma-Aldrich

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)

Synonym: [(iPr)CuCl], [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) chloride

  • CAS Number 578743-87-0

  • Empirical Formula (Hill Notation) C27H36ClCuN2

  • Molecular Weight 487.59

  •  MDL number MFCD09264276

  •  PubChem Substance ID 329761816

  •  NACRES NA.22

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper Catalysts More...
Quality Level   100
mp   >300 °C
reaction suitability   reagent type: catalyst
SMILES string   CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=[Cu]\Cl)c3c(cccc3C(C)C)C(C)C
InChI   1S/C27H36N2.ClH.Cu/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;1H;/q;;+1/p-1
InChI key   JPUFNIIPFXQOCB-UHFFFAOYSA-M

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes."

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number
Protocols & Articles

Articles

N-Heterocyclic Carbene-Copper Complexes

N-heterocyclic carbene ligands have proven very popular in the last 20 years. The electronic and steric modularity associated with the resulting complexes have made NHCs obvious candidates when desig...
Josephine Nakhla
ChemFiles 2009, 9.2, 16.
Keywords: Aldrichimica Acta, Catalysis, Cyclopropanations, Hydrosilylations, Ligands, Methylenations, Olefinations, Reductions

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?