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  • 696501 - Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)

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696501 Sigma-Aldrich

Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)

95%

Synonym: 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene gold(I) chloride

  • CAS Number 852445-81-9

  • Empirical Formula (Hill Notation) C21H24AuClN2

  • Molecular Weight 536.85

  •  MDL number MFCD11656059

  •  PubChem Substance ID 329761834

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
Quality Level   100
assay   95%
reaction suitability   core: gold
  reagent type: catalyst
mp   >300 °C
storage temp.   2-8°C
SMILES string   Cl[Au].Cc1cc(C)c(N2[C]N(C=C2)c3c(C)cc(C)cc3C)c(C)c1
InChI   1S/C21H24N2.Au.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;;/h7-12H,1-6H3;;1H/q;+1;/p-1
InChI key   YFUIKJIITPMUAT-UHFFFAOYSA-M

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Packaging

100, 500 mg in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

N-Heterocyclic Carbene-Copper Complexes

N-heterocyclic carbene ligands have proven very popular in the last 20 years. The electronic and steric modularity associated with the resulting complexes have made NHCs obvious candidates when desig...
Josephine Nakhla
ChemFiles 2009, 9.2, 16.
Keywords: Aldrichimica Acta, Catalysis, Cyclopropanations, Hydrosilylations, Ligands, Methylenations, Olefinations, Reductions

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