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697311 Sigma-Aldrich

Cyclopropylboronic acid MIDA ester

97%

Synonym: Cyclopropylboronic acid methyliminodiacetic acid anhydride

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Properties

Related Categories Alkyl MIDA Boronates, Boronic Acids and Derivatives, Chemical Synthesis, MIDA Boronates, Organometallic Reagents More...
InChI Key   LLXFTRDFBQZFSN-UHFFFAOYSA-N
assay   97%
mp   183-193 °C
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

MIDA Boronates for Suzuki–Miyaura Cross-Couplings

Professor Martin Burke and coworkers recently prepared retinal using key MIDA building block BB1 in iterative Suzuki-Miyaura cross coupling reactions (Scheme 1). The MIDA unit of BB1 is unreactive un...
Aaron Thornton
ChemFiles Volume 11 Article 1
Keywords: Building blocks, Coupling reactions, Cross couplings, Solvents

Synthetic Utility of Vinyl MIDA Boronate

The utility of vinyl MIDA boronate was demonstrated via cyclopropanation and epoxidation to the corresponding MIDA cyclopropane and oxirane, respectively. These procedures (Scheme 13) provided air an...
Josephine Nakhla
ChemFiles Volume 9 Article 1
Keywords: Chromatography, Cross metathesis, Cyclopropanations, Epoxidations, Metathesis, Olefin metathesis, Purification, transformation

Related Content

New MIDA Boronates from Aldrich

MIDA boronates are stable boronic acid surrogates used for Suzuki-Miyaura cross-coupling reactions. These reagents enable the coupling of historically unstable organoboron species; including those co...
Keywords: Aldrichimica Acta, Coupling reactions, Cross couplings, Nuclear magnetic resonance spectroscopy

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