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697591 Sigma-Aldrich

(R,R)-ANDEN-Phenyl Trost Ligand

technical grade

Synonym: (+)-(11R,12R)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene, (11R,12R)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands More...
grade   technical grade
optical activity   [α]22/D -100°, c = 1 in chloroform
mp   125-130 °C
SMILES string   O=C(N[C@H]1[C@H](NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)[C@H]5c6ccccc6[C@@H]1c7ccccc57)c8ccccc8P(c9ccccc9)c%10ccccc%10
InChI   1S/C54H42N2O2P2/c57-53(45-33-17-19-35-47(45)59(37-21-5-1-6-22-37)38-23-7-2-8-24-38)55-51-49-41-29-13-15-31-43(41)50(44-32-16-14-30-42(44)49)52(51)56-54(58)46-34-18-20-36-48(46)60(39-25-9-3-10-26-39)40-27-11-4-12-28-40/h1-36,49-52H,(H,55,57)(H,56,58)/t49-,50+,51-,52-/m1/s1
InChI key   BEKZNCOFLFMFHP-HRHVFIINSA-N

Description

Application

Catalyst involved in asymmetric allylic alkylations

Asymmetric allylic alkylation ligand.

Packaging

100 mg in glass bottle

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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