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  • 698350 - 1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

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698350 Sigma-Aldrich

1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Synonym: (R,R)-Ph-BPE-Rh

  • CAS Number 528565-84-6

  • Empirical Formula (Hill Notation) C42H48BF4P2Rh

  • Molecular Weight 804.49

  •  MDL number MFCD07369037

  •  PubChem Substance ID 329762005

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes More...
Quality Level   100
SMILES string   [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2C[C@@H](P(CCP3[C@H](CC[C@@H]3c4ccccc4)c5ccccc5)[C@H]2c6ccccc6)c7ccccc7
InChI   1S/C34H36P2.C8H12.BF4.Rh/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-20,31-34H,21-26H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t31-,32-,33-,34-;;;/m1.../s1
InChI key   HOYBXERAQSXVFT-FMUQXVHFSA-N

Description

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Packaging

50, 250 mg in amber glass bottle

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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