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698997 Sigma-Aldrich

Poly(3-hexylthiophene-2,5-diyl)

regioregular, average Mn 54,000-75,000, electronic grade, 99.995% trace metals basis

Synonym: P3HT, Plexcore® OS 2100

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Properties

Related Categories π-Conjugated Polymers, 3D Printing Materials for Research and Development, Bioelectronics, Biosensing and Bioimaging, Conductive Polymers,
grade   electronic grade
assay   99.995% trace metals basis
form   solid
mol wt   average Mn 54,000-75,000
description   (>98% head-to-tail regioregular (HNMR))
mp   238 °C
Orbital energy   HOMO 5 eV 
  LUMO 3 eV 
OPV Device Performance   ITO/NiO/P3HT/PC61BM/LiF/Al
• Short-circuit current density (Jsc): 11.3 mA/cm2
• Open-circuit voltage (Voc): 0.64 V
• Fill Factor (FF): 0.69
• Power Conversion Efficiency (PCE): 5.16 %
  ITO/PEDOT:PSS/P3HT:PC61BM (1:08)/Al
• Short-circuit current density (Jsc): 9.5 mA/cm2
• Open-circuit voltage (Voc): 0.63 V
• Fill Factor (FF): 0.68
• Power Conversion Efficiency (PCE): 5 %
Mw/Mn   ≤2.5
semiconductor properties   P-type (mobility=10−4 - 10−1 cm2/V·s)

Description

General description

LUMO level 3.1 eV

Poly(3-hexylthiophene) (P3HT) is a regioregular semiconducting polymer. It is used in organic electronics primarily because of its regular end-to-end arrangement of side chain, which allows efficient Π-Π stacking of the conjugated backbones. On account of the alkyl side group, P3HT is rendered hydrophobic in neutral state.

Packaging

1, 5 g in glass bottle

250 mg in poly bottle

Legal Information

Product of Plextronics, Inc. U.S. Patent 6,166,172.

Plexcore is a registered trademark of Plextronics, Inc.

Application

Polmer-based Materials for Printed Electronics: Enabling High Efficency Solar Power and Lighting

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

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Protocols & Articles

Articles

3D Printing of Carbon Fiber-Reinforced Composites

3D printing is a type of additive manufacturing that can be used to rapidly fabricate components with highly customizable geometries, most typically using a layer-by-layer fabrication process. 3D pri...
Zhenyu Bo* (Ph.D Candidate at Northwestern University) and Jia Choi*, PhD, Product Manager


*Materials Science Product Management Team, MilliporeSigma, Milwaukee, WI.
Keywords: Deposition, Nanomaterials, Nanotubes

Applications of Conducting Polymer Devices in Life Sciences

Leslie H. Jimison1, Dion Khodagholy1, Thomas Doublet1,2, Christophe Bernard2, George G. Malliaras1, and Róisín M. Owens1 1Department of Bioelectronics, Ecole Nationale Supérieure des Mines CMP-EMSE, ...
Keywords: Bacterial conjugations, Cancer, Cell culture, Diagnostic, Diffusion, Electronics, Gastrointestinal, Immunofluorescence, Organic electronics, Semiconductor, Spectroscopy

Nanoparticle-based Zinc Oxide Electron Transport Layers for Printed Organic Photodetectors

Gerardo Hernandez-Sosa,1,2* Ralph Eckstein,1,2 Tobias Rödlmeier,1,2 Uli Lemmer1,2,3 1Lichttechnisches Institut, Karlsruher Institut für Technologie, Engesserstrasse 13, 76131 Karlsruhe, Germany 2Inno...
Gerardo Hernandez-Sosa*, Ralph Eckstein, Tobias Rödlmeier, Uli Lemmer
Material Matters, 2016, 11.2
Keywords: Deposition, Electronics, Positron Emission Tomography, Recombination, Reductions, Solar cells, Thin film deposition

Novel Graphene‑Based Nanostructures Production, Functionalization, and Engineering

Manuela Melucci,1 Simone Ligi,2 Vincenzo Palermo3* 1ISOF – Consiglio Nazionale delle Ricerche (CNR), Italy 2GNext sas, Italy 3ISOF – Consiglio Nazionale delle Ricerche (CNR), Italy *Email: vincenzo.p...
Keywords: Absorption, Asymmetric synthesis, Catalysis, Deposition, Electronics, Evaporation, Nucleic acid annealing, Oxidations, Reductions, Semiconductor, Silylations, Solvents, Sonication

Optoelectronic Devices Based on Diketopyrrolopyrrole (DPP)-containing Conjugated Small Molecules

Optoelectronic devices such as light-emitting diodes (LEDs), solar cells, and light-emitting field effect transistors (FETs) that utilize organic materials as their light harvesting and/or charge tra...
Jianhua Liu and Thuc-Quyen Nguyen
Material Matters 7.1
Keywords: Absorption, Alkylations, Applications, Bacterial conjugations, Biochemistry, Brominations, Building blocks, Capabilities, Nucleic acid annealing, Nucleic acid hybridization, Purification, Recombination, Solar cells, Solvents, Spectra, Spectroscopy, Stille coupling, Support, Suzuki coupling, Type, Ultraviolet-Visible spectroscopy

Organic Materials for Thin Film Transistors

Flexible electronic circuits, displays, and sensors based on organic active materials will enable future generations of electronics products that may eventually enter the mainstream electronics marke...
Prof. Zhenan Bao
Material Matters 2007, 2.3, 4.
Keywords: Building blocks, Deposition, Electronics, Nanotubes, Semiconductor

Polymer-based Materials for Printed Electronics: Enabling High Efficiency Solar Power and Lighting

The soaring global demand for energy has created an urgent need for new energy sources that are both cost-competitive and eco-friendly. Renewable energy technology, such as solar power and energy eff...
Ritesh Tipnis*, Darin Laird, Mathew Mathai
Material Matters 2008, 3.4, 92.
Keywords: Absorption, Degradations, Deposition, Electronics, Environmental, Infrared spectroscopy, Organic electronics, PAGE, Photovoltaics, Polymerization reactions, Printed electronics, Recombination, Reductions, Renewable energy, Semiconductor, Separation, Solar cells, Spin coating

Recent Advances in Hybrid Halide Perovskites-based Solar Cells

Kuppuswamy Kalyanasundaram, Shaik. M. Zakeeruddin, Michaël Grätzel* Laboratory for Photonics and Interfaces (LPI) Swiss Federal Institute of Technology at Lausanne (EPFL) 1015 Lausanne, Switzerland *...
Kuppuswamy Kalyanasundaram, Shaik. M. Zakeeruddin, Michaël Grätzel
Material Matters, 2016, 11.1, 3
Keywords: Absorption, Atomic layer deposition, Capillary electrophoresis, Degradations, Deposition, Diffusion, Environmental, Infrared spectroscopy, Nanomaterials, Nanotubes, Nucleic acid annealing, Recombination, Semiconductor, Separation, Sol-gel, Solar cells, Solvents, Spectroscopy, Spin coating, Substitutions

Self-Assembly in Organic Thin Film Transistors for Flexible Electronic Devices

Flexible electronic circuits and displays based on organic active materials are future generations of products that may eventually enter mainstream electronics market. The advantages in using organic...
Professor Zhenan Bao
Material Matters 2006, 1.2, 11.
Keywords: Applications, Building blocks, Crystallization, Deposition, Electronics, Methods, Polymerization reactions, Semiconductor, Spin coating

Understanding and Successfully Applying Materials for Dye-Sensitized Solar Cells

Hans Desilvestro, Yanek Hebting, Mikael Khan, Damion Milliken Dyesol, Queanbeyan NSW 2620, Australia Email: yhebting@dyesol.com
Keywords: Absorption, Adhesion, Adsorption, Bacterial conjugations, Calorimetry, Deposition, Diffusion, Electronics, Extinction coefficient, Hydroxylations, Ligands, Mass spectrometry, Nucleic acid annealing, Oxidations, PAGE, Printed electronics, Recombination, Reductions, Semiconductor, Solar cells, Solvents

Protocols

Preparation of Photoactive Layer for Organic Photovoltaic Applications

Plexcore OS 2100, a p-type polymer semiconductor, is a high molecular weight, highly regioregular grade of P3HT that is optimized for Organic Photovoltaics (OPV) applications. It can be combined with...
Keywords: Deposition, Nuclear magnetic resonance spectroscopy, Photovoltaics, Renewable energy, Semiconductor, Solvents, Spin coating

Peer-Reviewed Papers
15

References

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900550 Poly(3-hexylthiophene-2,5-diyl), regioregular, average Mw 50,000-75,000

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