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700223 Sigma-Aldrich

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

97%

Synonym: Mn(TMHD)3, Mn(dpm)3, Shenvi Hydrogenation Catalyst, Tris(dipivaloylmethanato)manganese

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese, Manganese Catalysts, Non-Precious Metal Catalysis More...
assay   97%
reaction suitability   core: manganese
  reagent type: catalyst
mp   160-170 °C
storage temp.   room temp
SMILES string   CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI   1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InChI key   ORZPLLPBZHORSD-LWTKGLMZSA-K

Description

Application

Catalyst for:
• Intramolecular Diels-Alder reactions
• Single electron donor for excess electron transfer studies in DNA
• Enantioselective synthesis
• Borylation reactions
• Hydrohydrazination and hydroazidation
• Oxidative carbonylation of phenol

Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
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