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  • 700665 - (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

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700665 Sigma-Aldrich

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Synonym: (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids
InChI Key   BVICVEIKBNVROI-UHFFFAOYSA-N
optical activity   [α]22/D −44.0°, c = 1 in DMSO
mp   390-400 °C
storage temp.   −20°C

Description

Packaging

100 mg in amber glass bottle

Application

Catalyst for:
• Asymmetric hydrogenation cascade
• Enantioselective Friedel-Crafts reaction
• Asymmetric hydrogenation of 2-substituted quinolines
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
• Asymmetric transfer hydrogenation of substituted quinoxalines

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
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