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701122 Sigma-Aldrich

Iron(III) chloride

sublimed grade, ≥99.9% trace metals basis

Synonym: Ferric chloride, Iron trichloride, Molysite

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Iron, Iron Catalysts,
Quality Level   100
grade   sublimed grade
vapor density   5.61 (vs air)
vapor pressure   1 mmHg ( 194 °C)
assay   ≥99.9% trace metals basis
form   powder or crystals
reaction suitability   reagent type: catalyst
core: iron
mp   304 °C (lit.)
Featured Industry   Battery Manufacturing
SMILES string   Cl[Fe](Cl)Cl
InChI   1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI key   RBTARNINKXHZNM-UHFFFAOYSA-K

Description

Application

Iron(III) chloride may be employed for the synthesis of polypyrrole via polymerization reaction. It may be employed as catalyst for the intramolecular oxidative coupling for the preparation of phenanthrene ring. It is a cheap, eco-friendly oxidizing reagent useful for the following organic reactions:
• polymerizations
• oxidations
• oxidative couplings
• reductions
• C-C bond formation
• Ferrier rearrangement
• multicomponent condensations
• Friedel-Crafts reactions
• cyclization′s
• glycosidation
• Prins-type cyclization

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

Packaging

1, 5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Personal Protective Equipment 
RIDADR 
UN 1773 8 / PGIII
WGK Germany 
WGK 1
RTECS 
LJ9100000
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Lithium-Ion Battery Performance: Dependence on Material Synthesis and Post‑Treatment Methods

Dr. Qifeng Zhang, Mr. Evan Uchaker, and Dr. Guozhong Cao* Department of Materials Science and Engineering University of Washington Seattle, WA 98195-2120 *Email: gzcao@u.washington.edu
Keywords: Absorption, Deposition, Diffraction, Diffusion, Electrochemical reactions, Materials Science, Nanomaterials, Nanotubes, Nucleic acid annealing, Oxidations, Precipitation, Redox Reactions, Reductions, X-Ray diffraction

Synthesis of Gold Nanorods: Avoiding Common Pitfalls

NanoHybrids Inc. 3913 Todd Ln #310, Austin, TX 78744, USA *Email: kimberly.homan@nanohybrids.net
Brantley C. Henson, Justin T. Harris, Kimberly A. Homan*
Material Matters, 2017, 12.1
Keywords: AGE, Absorption, Addition reactions, Asymmetric synthesis, Centrifugation, Clinical, Degradations, Deposition, Indicators, Industries, Infrared spectroscopy, Ligands, Microscopy, Precipitation, Purification, Reductions, Scanning electron microscopy, Separation, Spectroscopy, Transmission electron microscopy

Synthesis of Magnetic Nanoparticles for Biosensing

Department of Chemistry and the Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road, Houston, Texas 77204-5003, United States *E-mail: trlee@uh.edu
Keywords: Catalysis, Diffraction, Immobilization, Ligands, Mass spectrometry, Microscopy, Nanomaterials, Nuclear magnetic resonance spectroscopy, Precipitation, Sample preparations, Scanning electron microscopy, Spectroscopy, Transmission electron microscopy, X-Ray diffraction

Peer-Reviewed Papers
15

References

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