• USA Home
  • 702005 - 1,1′-Bis(di-isopropylphosphino)ferrocene palladium dichloride

EMAIL THIS PAGE TO A FRIEND
702005 Sigma-Aldrich

1,1′-Bis(di-isopropylphosphino)ferrocene palladium dichloride

98%

Synonym: PdCl2(dippf)

  • CAS Number 215788-65-1

  • Empirical Formula (Hill Notation) C22H36Cl2FeP2Pd

  • Molecular Weight 595.64

  •  MDL number MFCD11656082

  •  PubChem Substance ID 329762338

  •  NACRES NA.22

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
Quality Level   100
assay   98%
mp   282-287 °C
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
storage temp.   −20°C
SMILES string   [Fe].Cl[Pd]Cl.CC(C)P([C]1[CH][CH][CH][CH]1)C(C)C.CC(C)P([C]2[CH][CH][CH][CH]2)C(C)C
InChI   1S/2C11H18P.2ClH.Fe.Pd/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;;;;/h2*5-10H,1-4H3;2*1H;;/q;;;;;+2/p-2
InChI key   UXOSTJATWDHIKQ-UHFFFAOYSA-L

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Articles

Amination of Aryl Halides

The Buchwald-Hartwig amination reaction, or the coupling between an aryl halide and an amine, is extremely important in various areas of both academic and industrial research. The amination of aryl c...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 11.
Keywords: Aminations, Buchwald-Hartwig amination, Catalysis, Chemfiles, Ligands

BRIDP Catalysts

Researchers at Takasago developed two phosphine-based ligands for the Buchwald-Hartwig amination reaction with successful results for the cross-coupling of a wide array of amines and aryl halides. Th...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 11.
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Chemfiles, Cross couplings, Electronics, Ligands

Ferrocenyl Based Ligands and Catalysts

Hartwig and co-workers have reported the use of the electron-rich and bulky ligand 1,1’-bis(di-tert-butylphosphino)ferrocene for the amination of aryl halides and for the first amination of aryl tosy...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 11.
Keywords: Aminations, Catalysis, Chemfiles, Eliminations, Ligands, Oxidative additions, Reductive eliminations

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?