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704091 Sigma-Aldrich

Tributyltin hydride solution

1 M in cyclohexane

Synonym: Tributylstannane, Tributylstannyl hydride

  • CAS Number 688-73-3

  • Empirical Formula (Hill Notation) C12H28Sn

  • Molecular Weight 291.06

  •  MDL number MFCD00009416

  •  PubChem Substance ID 329762093

  •  NACRES NA.22

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Properties

Related Categories Chemical Synthesis, Metal Hydrides, Reduction, Synthetic Reagents
Quality Level   100
concentration   1 M in cyclohexane
refractive index   n20/D 1.438
density   0.895 g/mL at 25 °C
SMILES string   CCCC[SnH](CCCC)CCCC
InChI   1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;
InChI key   DBGVGMSCBYYSLD-UHFFFAOYSA-N

Description

Application

Reactant or reagent for:
• Alkyne hydrostannations
• Intramolcular cyclization for the synthesis of zoanthamine alkaloids
• Stereoselective C-glycosylation of pyranosides using Heck allylation
• Synthesis of phenylbutenoid dimers for use in treating diseases
• Preparation of N-acyl derivatives of ecteinascidin 770
• Syntehsis of cyclonucleosides using black light induced radical cyclization

Packaging

10, 50 mL in glass bottle

Safety & Documentation

Safety Information

Signal word 
Danger
Target organs 
Central nervous system
RIDADR 
UN 1993BE 3 / PGII
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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