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704415 Aldrich

Vinylboronic acid MIDA ester


Synonym: 6-Methyl-2-vinyl-1,3,6,2-dioxazaborocane-4,8-dione



Related Categories Alkenyl MIDA Boronates, Boronic Acids and Derivatives, Chemical Synthesis, MIDA Boronates, Organometallic Reagents More...
assay   97%
mp   152-156 °C
storage temp.   2-8°C

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Protocols & Articles


MIDA Boronates for Suzuki–Miyaura Cross-Couplings: Application

Burke and coworkers recently prepared retinal using newly-developed methodology, which employs boronic acid surrogates, termed MIDA boronates (retinal synthesis employed key MIDA building block BB1—S...
Dr. Josephine Nakhla
Chemfiles Volume 10 Article 1
Keywords: Building blocks, Coupling reactions, Cross couplings, Solvents

MIDA Boronates for Suzuki–Miyaura Cross-Couplings

Professor Martin Burke and coworkers recently prepared retinal using key MIDA building block BB1 in iterative Suzuki-Miyaura cross coupling reactions (Scheme 1). The MIDA unit of BB1 is unreactive un...
Aaron Thornton
ChemFiles Volume 11 Article 1
Keywords: Building blocks, Coupling reactions, Cross couplings, Solvents

MIDA-protected Boronate Esters

The Suzuki-Miyaura cross-coupling reaction is one of the most important and highly utilized reactions in organic chemistry, with applications in polymer science as well as in the fine chemicals and p...
Josephine Nakhla
ChemFiles Volume 9 Article 1
Keywords: Aminations, Applications, Bromoborations, Building blocks, Catalysis, Chemfiles, Chromatography, Coupling reactions, Cross couplings, Cross metathesis, Cyclopropanations, Epoxidations, Industries, Ligands, Metathesis, Methods, Natural product synthesis, Olefin metathesis, Pharmaceutical, Polymer science, Protocols, Purification, Reductions, Reductive aminations, Stille coupling, Suzuki coupling, Suzuki reactions, Takai olefination, Transmetalation, Type, transformation

Preparation of trans-(2-bromovinyl) MIDA Boronate and Vinyl MIDA Boronate from the Corresponding Silanes

Due to the instability of some boronic acids, the Burke group has developed very practical syntheses of some of the more challenging MIDA boronates. For instance, while trans-(2-bromovinyl) MIDA boro...
Josephine Nakhla
ChemFiles Volume 9 Article 1
Keywords: Bromoborations, Building blocks, Transmetalation

Related Content

New MIDA Boronates from Aldrich

MIDA boronates are stable boronic acid surrogates used for Suzuki-Miyaura cross-coupling reactions. These reagents enable the coupling of historically unstable organoboron species; including those co...
Keywords: Aldrichimica Acta, Coupling reactions, Cross couplings, Nuclear magnetic resonance spectroscopy

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